MICELLAR EFFECTS UPON THE REACTION BETWEEN ACETONITRILE PENTACYANOFERRATE(II) AND THYLENEDIAMMINE)(2-PYRAZINECARBOXYLATO)COBALT(III)

Authors
PRADOGOTOR R JIMENEZ R LOPEZ P PEREZ P GOMEZHERRERA C SANCHEZ F
Citation
R. Pradogotor et al., MICELLAR EFFECTS UPON THE REACTION BETWEEN ACETONITRILE PENTACYANOFERRATE(II) AND THYLENEDIAMMINE)(2-PYRAZINECARBOXYLATO)COBALT(III), Langmuir, 14(7), 1998, pp. 1539-1543
Citations number
15
Categorie Soggetti
Chemistry Physical
Journal title
Langmuir → ACNP
ISSN journal
07437463
Volume
14
Issue
7
Year of publication
1998
Pages
1539 - 1543
Database
ISI
SICI code
0743-7463(1998)14:7<1539:MEUTRB>2.0.ZU;2-T
Abstract
The substitution reaction of ethylenediammine(2-pyrazinecarboxylato)co balt(III) for acetonitrile ligand in acetonitrile pentacyanoferrate(II ) was studied in micellar solutions of sodium dodecyl sulfate. The res ults are interpreted considering the influence of the electric geld in the micellar interfacial region on the formation of the encounter com plex between the reactants. The influence of the field on the reverse (dissociation) process is also discussed.