STEREOSELECTIVE MANGANESE-CATALYZED COUPLING REACTION OF CONJUGATED CHLOROENYNES AND CHLORODIENES WITH GRIGNARD-REAGENTS

Authors
ALAMI M RAMIANDRASOA P CAHIEZ G
Citation
M. Alami et al., STEREOSELECTIVE MANGANESE-CATALYZED COUPLING REACTION OF CONJUGATED CHLOROENYNES AND CHLORODIENES WITH GRIGNARD-REAGENTS, Synlett, (3), 1998, pp. 325-327
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
3
Year of publication
1998
Pages
325 - 327
Database
ISI
SICI code
0936-5214(1998):3<325:SMCROC>2.0.ZU;2-1
Abstract
In the presence of the soluble complex MnCl2 . 2LiCl (3%), conjugated chloroenynes and chlorodienes readily react with alkyl Grignard reagen ts in THF-DMPU to afford stereoselectively enynes and dienes in good t o excellent isolated yields.