An excited well-deformed rotational band has been observed in the N =
Z odd-odd nucleus Cu-58. The first excited state in this band decays v
ia gamma emission to the spherical states associated with the first mi
nimum in the potential, thus providing for its unambiguous assignment
to Cu-58. I, contrast, its bandhead decays via emission of a prompt 2.
4(1) MeV proton to an excited state in the daughter nucleus Ni-57. Thi
s is the first observation of proton decay from states associated with
a deformed secondary minimum in the potential. Self-consistent Hartre
e-Fock calculations reproduce well both the large collectivity of this
band and the general trend of its moment of inertia.