PROTONATION-INDUCED LIGAND SWITCHING WITHIN NO2+ BOUND CLUSTERS

Authors
DEPETRIS G PEPI F
Citation
G. Depetris et F. Pepi, PROTONATION-INDUCED LIGAND SWITCHING WITHIN NO2+ BOUND CLUSTERS, Chemical physics letters, 285(5-6), 1998, pp. 366-372
Citations number
28
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
285
Issue
5-6
Year of publication
1998
Pages
366 - 372
Database
ISI
SICI code
0009-2614(1998)285:5-6<366:PLSWNB>2.0.ZU;2-E
Abstract
An intracluster proton-promoted reaction leading to a ligand switching in mixed NO2+ complexes of nitric acid and its derivatives is describ ed. The proton affinity and the NO2+ binding energy are demonstrated t o be the factors affecting the process, the trend of which is shown to reflect the peculiar properties of nitric acid and its derivatives. ( C) 1998 Elsevier Science B.V.