The phenomenon of high-field domain formation and expansion along a su
perlattice/multi-quantum well system has been known since the first pi
oneering works on these structures. Experimentally it has usually been
observed by monitoring negative differential resistance oscillations
in the electric characteristics (I-V curves) of the samples. It is due
to the fact that a uniform field distribution becomes unstable with r
espect to the formation of high and low electric field domains. When i
ncreasing the applied field, one can observe the progressive inducemen
t of additional quantum well periods into the high-held domain, at vol
tages correlated with the alignment energies and with the periods of t
he oscillations in the I-V characteristics. Recently, optical tools we
re used to probe, in a more direct way, the field distributions along
such systems. These experiments can be performed using interband or in
tersubband spectroscopies. The behaviour of electric field configurati
ons along superlattices/multi-quantum well structures is strongly link
ed to the availability of free-space charge. Heavy doping or strong il
lumination providing this charge will induce stable field configuratio
ns. A supply of charge which is less than needed may result in a spati
al oscillation of space charge among different sites. The regime of lo
west charge supply can produce transient field domains resulting in sp
ontaneous current oscillations reminiscent of transferred electron dev
ices and Gunn diodes; however, the negative differential resistance dr
iving the effect originates from low-dimensional transport properties
rather than from bulk inter-valley transfer. In addition to its import
ance for transport studies, the presence of space-charge accumulation
at definite sites along a superlattice/multi-quantum well system, toge
ther with the presence of different field domains, raise the possibili
ty of spatial control, localization and/or modulation of optical nonli
near effects along such structures. We review previous studies, which
used intersubband spectroscopy to study field domain Switching, and pr
esent new results on how to use photoluminescence quenching of interba
nd transitions, under the application of an applied field, to further
investigate domain formation and expansion in multi-stack samples.