Je. Parks et al., IN-SITU MEASUREMENT OF FUEL IN THE CYLINDER WALL OIL FILM OF A COMBUSTION ENGINE BY LIF SPECTROSCOPY, Applied spectroscopy, 52(1), 1998, pp. 112-118
Hydrocarbon emissions remain an important concern for the automotive i
ndustry due to increasingly strict regulations. In an investigation of
possible emission sources within the engine, the concentration of fue
l absorbed in the oil film on the cylinder wall of a small internal co
mbustion engine has been measured with laser-induced fluorescence (LIF
) spectroscopy, A laser pulse from a nitrogen laser (337.1 nm) provide
d the excitation, and the fluorescence was monitored with an intensifi
ed-charge-coupled device (ICCD) array mounted to a spectrometer. The e
xcitation laser pulse was launched through a window in the engine head
onto a fiber-optic probe mounted flush with the cylinder wall. The la
ser-excited oil film on the fiber-optic probe produced an LIF signal t
hat was collected by the fiber-optic probe and analyzed for fuel conte
nt. The timing of the laser pulse and ICCD gate were controlled in ord
er to synchronize the collection of data with a particular point in th
e engine cycle. Measurements made in situ, while the engine was runnin
g, yield information on the amount of unburned fuel stored in the oil
film for various engine conditions. Fuel-in-oil concentrations were de
termined for various engine temperatures during cold starts, for diffe
rent fuel enrichment levels, and as a function of the crank angle of t
he engine cycle. Fuel concentrations as high as 50% were detected duri
ng cold starts, and fuel concentrations reached levels greater than 25
% for warm engine operation. Changes in the fuel content were also fou
nd to be related to enrichment and crank angle.