FIRST ISOLATION AND CHARACTERIZATION OF SULFENIUM CATION SALTS STABILIZED BY THE COORDINATION OF 2 NITROGEN-ATOMS

Authors
KOBAYASHI K SATO S HORN E FURUKAWA N
Citation
K. Kobayashi et al., FIRST ISOLATION AND CHARACTERIZATION OF SULFENIUM CATION SALTS STABILIZED BY THE COORDINATION OF 2 NITROGEN-ATOMS, Tetrahedron letters, 39(17), 1998, pp. 2593-2596
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
17
Year of publication
1998
Pages
2593 - 2596
Database
ISI
SICI code
0040-4039(1998)39:17<2593:FIACOS>2.0.ZU;2-Y
Abstract
The remarkably stable sulfenium cation salts were prepared from the re action of 2,6-bis(dimethylamino)methyl-1-lithiobenzene with sulfur dic hloride. These compounds have been characterized by various NMR and el emental analysis. A single crystal X-ray structure determination revea led that two amino groups coordinate directly to the cationic sulfur a tom. (C) 1998 Elsevier Science Ltd. All rights reserved.