G. Stevens et al., METAMORPHISM, FLUID-FLOW, AND GOLD MOBILIZATION IN THE WITWATERSRAND BASIN - TOWARDS A UNIFYING MODEL, South African journal of geology, 100(4), 1997, pp. 363-375
Recent advances in the understanding of metamorphism in the Witwatersr
and Basin, particularly in the previously deeply buried central portio
ns now exposed in the Vredefort Dome, here contribute to the developme
nt of a basin-wide metamorphic model. Low-pressure, high-temperature p
eak metamorphic conditions were attained throughout the basin during t
he crustal thermal perturbation associated with the Bushveld Event. Du
ring this event, prograde devolatilization reactions in the predominan
tly argillitic West Rand Group produced pulses of aqueous fluids. Phas
e proportion calculations indicate that in an average West Rand Group
shale composition, where peak metamorphic temperatures were high enoug
h for the complete reaction of chlorite + muscovite to biotite (simila
r to 450 degrees C), 70 litres of hydrous fluid would have been produc
ed per cubic metre of rock. In these rocks further breakdown of hydrou
s minerals to produce the peak metamorphic assemblage recorded in the
collar of the Vredefort Dome (similar to 600 degrees C), would have li
berated an additional 69 litres of hydrous metamorphic fluid per cubic
metre of rock. These calculations, coupled to the peak metamorphic th
ermal profile through the basin and the known sub-outcrop limits of th
e West Rand Group suggest that at least 7.58 x 10(14) litres of metamo
rphic fluid was evolved from within the presently preserved West Rand
Group. Data from alteration assemblages and fluid inclusion studies in
gold-bearing reef horizons of the Central Rand Group near the basin m
argins indicate that fluid flow occurred close to the peak of metamorp
hism, as predicted by the modelling of metamorphism in the West Rand G
roup. Calculated gold solubility in the measured fluid inclusion compo
sitions is between 1 and 10 parts per billion. Thus, metamorphic fluid
s derived from within the presently preserved lower portions of the Wi
twatersrand Supergroup had the potential to mobilize at least 7600 ton
s of gold. In this paper it is proposed that this metamorphic fluid de
rived from within the basin mobilized and redistributed a significant
portion of the pre-existing gold concentrations, resulting in many of
the features interpreted to be in support of an epigenetic origin for
the entire deposit.