Hal. Kiers et Ak. Smilde, CONSTRAINED 3-MODE FACTOR-ANALYSIS AS A TOOL FOR PARAMETER-ESTIMATIONWITH 2ND-ORDER INSTRUMENTAL DATA, Journal of chemometrics, 12(2), 1998, pp. 125-147
Three-mode factor analysis models are often used in exploratory analys
is of three-way data. However, in some situations it is a priori known
that a particular constrained three-mode factor analysis (C3MFA) mode
l describes an underlying process exactly. In such situations, fitting
a C3MFA model to a data set can be used for both quantitative analysi
s (e.g. estimating concentrations of a chemical substance in a mixture
) and qualitative analysis (e.g. on the basis of certain subsets of pa
rameters one can identify the substances present in a mixture). In thi
s paper a general algorithm for fitting a range of such C3MFA models i
s proposed. Whether C3MFA is used for qualitative or quantitative anal
ysis, in both cases it is crucial that the relevant parameter estimate
s are uniquely determinable. In the present paper it is discussed how
and to what extent uniqueness of certain model parameters can be asses
sed. (C) 1998 John Whey & Sons, Ltd.