J. Kelly et al., LASER CLADDING OF CAST ALUMINUM-SILICON ALLOYS FOR IMPROVED DRY SLIDING WEAR-RESISTANCE, Journal of laser applications, 10(2), 1998, pp. 45-54
AA333 specimens were hardfaced with mechanically mixed Mn-Al bronze po
wder by laser cladding to investigate its possible use in a boundary l
ubricated sliding application for better wear resistance. The coatings
needed to be more seizure resistant than the AA333 currently in use.
Like other cast aluminum alloys, AA333 possesses a hard, silicon rich
secondary phase which helps impart good wear properties. However, in s
tarved lubrication conditions, the relative softness and low melting p
oint of the Al-rich matrix can result in its scuffing and even seizure
. The laser used was a 6 kW cw CO2 laser, in an oscillating beam proce
ss. The experimental group of coatings consisted of a 3 X 3 matrix of
three process parameters-laser power, traverse speed, and powder feed.
The coatings were mechanically sound, relatively free of small cracks
and porosities, with a strong, tough metallurgical bond. The coatings
were 3 to 4 times harder than the AA333 substrate matrix which was ab
out 90 Vhn. Many wear specimens were prepared from the coatings for co
mparison with AA333 properties, and for property versus process parame
ter correlations within the experimental matrix of coatings. The coati
ng microstructure was primarily single phase, consisting of fcc column
ar-type grains of varying size produced by rapid and directional solid
ification, with a homogeneous distribution of the alloying elements in
solid solution (by wt %: 75 Cu, 12 Mn, 8 Al, 3 Fe, 2 Ni). Analysis of
coating microstructures was carried out using optical and scanning el
ectron microscopy, x-ray energy dispersive spectroscopy, and x-ray dif
fractometry. The interface microstructure was found to contain alpha-A
l (fcc) in the remelt layer and theta-CuAl2 (tetragonal). Tribological
tests showed that the seizure resistance of the coatings was superior
to AA333 in dry sliding tribological tests, though the wear rates of
the coatings show some dependence on the process parameters. The coati
ngs exhibited up to 1/3 the wear rate of the AA333 substrate under the
same dry wear test conditions of 4.5 kg normal load at 600 rpm, 30.3
mm radius of sliding, simulating actual component operation. However,
the major benefit of the coating is increased resistance to an abrupt,
work-stopping failure by seizure. Necessary repair and replacement of
parts as a result of seizure can be very costly. The wear mechanisms
of coatings and substrate are discussed, as are the coating properties
versus process parameters. (C) 1998 Laser Institute of America. [S104
2-336X(98)00202-2].