Under certain circumstances(1,2), a superconducting Josephson junction
can maintain a quantum phase difference of rr between the two samples
that are weakly connected to form the junction. Such systems are call
ed 'pi-junctions' and have formed the basis of several experiments des
igned to investigate the much-debated symmetry of the order parameter
of high-temperature superconductors(3-8) More recently, the possibilit
y that similar phenomena might occur in another macroscopic quantum sy
stem - a pair of weakly coupled Bose-Einstein condensates - has also b
een suggested(9). Here we report the discovery of a metastable superfl
uid state, in which a quantum phase difference of pi is maintained acr
oss a weak link separating two reservoirs of superfluid He-3. The exis
tence of this state, which is the superfluid analogue of a superconduc
ting pi-junction, is likely to reflect the underlying 'p-wave' symmetr
y of the order parameter of superfluid He-3, but a precise microscopic
explanation is at present unknown.