KINETICS AND MECHANISM OF THE ALKALINE-HYDROLYSIS OF 2,4-DINITROPHENYL 4'-HYDROXYPHENYLPROPIOLATE

Authors
CEVASCO G PARDINI R THEA S
Citation
G. Cevasco et al., KINETICS AND MECHANISM OF THE ALKALINE-HYDROLYSIS OF 2,4-DINITROPHENYL 4'-HYDROXYPHENYLPROPIOLATE, EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, (4), 1998, pp. 665-669
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY → ACNP
ISSN journal
1434193X
Issue
4
Year of publication
1998
Pages
665 - 669
Database
ISI
SICI code
1434-193X(1998):4<665:KAMOTA>2.0.ZU;2-J
Abstract
The alkaline hydrolysis of the title ester was studied in 40 % dioxane /water (v/v) solutions. Kinetic data, reactivity comparisons with mode l substrates and activation parameters appear to suggest the occurrenc e of a dissociative E1cB pathway although participation of the associa tive mechanism cannot be definitely ruled out.