REMARKS ON THE INFORMATION ENTROPY MAXIMIZATION METHOD AND EXTENDED THERMODYNAMICS

Authors
Citation
Bc. Eu, REMARKS ON THE INFORMATION ENTROPY MAXIMIZATION METHOD AND EXTENDED THERMODYNAMICS, The Journal of chemical physics, 108(14), 1998, pp. 5834-5844
Citations number
44
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
108
Issue
14
Year of publication
1998
Pages
5834 - 5844
Database
ISI
SICI code
0021-9606(1998)108:14<5834:ROTIEM>2.0.ZU;2-G
Abstract
The information entropy maximization method was applied by Jou er al. [J. Phys. A 17, 2799 (1984)] to heat conduction in the past. Advancing this method one more step, Nettleton [J. Chem. Phys. 106, 10311 (1997 )] combined the method with a projection operator technique to derive a set of evolution equations for macroscopic variables from the Liouvi lle equation for a simple liquid, and a claim was made that the method provides a statistical mechanical theory basis of irreversible proces ses and, in particular, of extended thermodynamics which is consistent with the laws of thermodynamics. This line of information entropy max imization method is analyzed from the viewpoint of the laws of thermod ynamics in this paper. (C) 1998 American Institute of Physics.