X-RAY STRUCTURE OF [LI(TMEDA)(2)][ZN(2,4, 6-IPR(3)C(6)H(2))(3)]

Authors
THIELE K GORLS H SEIDEL W
Citation
K. Thiele et al., X-RAY STRUCTURE OF [LI(TMEDA)(2)][ZN(2,4, 6-IPR(3)C(6)H(2))(3)], Zeitschrift fur anorganische und allgemeine Chemie, 624(4), 1998, pp. 555-556
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
624
Issue
4
Year of publication
1998
Pages
555 - 556
Database
ISI
SICI code
0044-2313(1998)624:4<555:XSO[6>2.0.ZU;2-4
Abstract
A side reaction of zinc halide containing VCl2(tmeda)(2) and Li(2,4,6- iPr(3)C(6)H(2)) formed [Li(tmeda)(2)][Zn(2,4,6-iPr(3)C(6)H(2))(3)]. 0. 5[(tmeda)Li(mu-Cl)](2). The crystal structure (orthorhombic, Pbca, a = 26,226(2), b = 19,739(2), c = 27,223(5) Angstrom, Z = 8, R = 0,062, W R2 = 0,154) contains trigonal planar zinc anions with Zn-C distances o f 2,039(7) Angstrom (average) and a propeller like arrangement of the aryl rings.