NOVEL DISCRETE STRUCTURE OF OXALATE-BRIDGED HETERONUCLEAR CR(III)-ND(III) COMPLEX

Authors
SAKAGAMI N OKAMOTO K
Citation
N. Sakagami et K. Okamoto, NOVEL DISCRETE STRUCTURE OF OXALATE-BRIDGED HETERONUCLEAR CR(III)-ND(III) COMPLEX, Chemistry Letters, (3), 1998, pp. 201-202
Citations number
24
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
3
Year of publication
1998
Pages
201 - 202
Database
ISI
SICI code
0366-7022(1998):3<201:NDSOOH>2.0.ZU;2-W
Abstract
A novel chromium(III)-neodymium (III) heteronuclear complex has been o btained by utilizing unsym-cis-[Cr(eddp)(ox)](-) as a building block. From the X-ray analysis, it is revealed that this complex is tetranucl ear in which the Nd(III) ion is bridged by three oxalates in the three Cr(III) units and three water molecules forming a nine-coordinate tri capped trigonal-prism geometry.