REACTIONS OF TETRACYANOETHYLENE OXIDE (TCNEO) WITH COBALTADITHIOLENE COMPLEXES

Authors
TAKAYAMA C TAKEUCHI K KAJITANI M SUGIYAMA T SUGIMORI A
Citation
C. Takayama et al., REACTIONS OF TETRACYANOETHYLENE OXIDE (TCNEO) WITH COBALTADITHIOLENE COMPLEXES, Chemistry Letters, (3), 1998, pp. 241-242
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
3
Year of publication
1998
Pages
241 - 242
Database
ISI
SICI code
0366-7022(1998):3<241:ROTO(W>2.0.ZU;2-#
Abstract
The reactions of cobaltadithiolene complexes bearing phenyl or ester l igands with tetracyanoethylene oxide (TCNEO) result in the formation o f dicyanomethylene-bridged complexes, via dicyanomethylide intermediat es. Furthermore, the reaction of cobaltadithiolene complex bearing 4-p yridyl ligands produces pyridinium dicyanomethylide complexes in good yields.