RHODIUM-CATALYZED INTRAMOLECULAR PAUSON-KHAND REACTION

Authors
KOGA Y KOBAYASHI T NARASAKA K
Citation
Y. Koga et al., RHODIUM-CATALYZED INTRAMOLECULAR PAUSON-KHAND REACTION, Chemistry Letters, (3), 1998, pp. 249-250
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
3
Year of publication
1998
Pages
249 - 250
Database
ISI
SICI code
0366-7022(1998):3<249:RIPR>2.0.ZU;2-P
Abstract
A rhodium dinuclear carbonyl complex, [RhCl(CO)(2)](2), serves as a ca talyst of the intramolecular Pauson-Khand reaction. 1,6-Enynes are con verted to cyclopentenone derivatives in high yield by heating in the p resence of the catalyst under an atmospheric pressure of CO.