THE SYNTHESIS AND STRUCTURE OF ([ETA(4)-ME(8)TAA]SN(MU-O))(2) - A BRIDGING OXO COMPLEX IN A SYSTEM THAT YIELDS TERMINAL SULFIDE AND SELENIDO COUNTERPARTS

Authors
KUCHTA MC HASCALL T PARKIN G
Citation
Mc. Kuchta et al., THE SYNTHESIS AND STRUCTURE OF ([ETA(4)-ME(8)TAA]SN(MU-O))(2) - A BRIDGING OXO COMPLEX IN A SYSTEM THAT YIELDS TERMINAL SULFIDE AND SELENIDO COUNTERPARTS, Chemical communications, (7), 1998, pp. 751-752
Citations number
37
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
7
Year of publication
1998
Pages
751 - 752
Database
ISI
SICI code
1359-7345(1998):7<751:TSASO(>2.0.ZU;2-X
Abstract
Oxo transfer from N2O to divalent [eta(4)-Me(8)taa]Sn (Me(8)taaH(2) = octamethyldibenzotetraaza[14]annulene) yields the oxo complex, {[eta(4 )-Me(8)taa]Sn(mu-O)}(2); the bridging nature of the oxo ligand provide s a marked contrast with the terminal sulfide and selenido counterpart s, [eta(4)-Me(8)taa]SnE(E = S, Se).