THE FIRST STABLE SCANDOCENE - SYNTHESIS AND CHARACTERIZATION OF T-BUTYL-1,3-DIPHOSPHACYCLOPENTADIENYL)SCANDIUM(II)

Authors
ARNOLD PL CLOKE FGN NIXON JF
Citation
Pl. Arnold et al., THE FIRST STABLE SCANDOCENE - SYNTHESIS AND CHARACTERIZATION OF T-BUTYL-1,3-DIPHOSPHACYCLOPENTADIENYL)SCANDIUM(II), Chemical communications, (7), 1998, pp. 797-798
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
7
Year of publication
1998
Pages
797 - 798
Database
ISI
SICI code
1359-7345(1998):7<797:TFSS-S>2.0.ZU;2-B
Abstract
The first isolable example of a molecular scandium(II) complex, the da rk purple scandocene [Sc(eta(5)-P2C3Bu3t)] 1, has been isolated from t he cocondensation of scandium vapour with tert-butylphosphaalkyne, (Bu CP)-C-t at 77 K.