MAGNETIC COMMUNICATION IN ACYCLIC MIXED-VALENCE TRIMOLYBDENUM COMPLEXES MEDIATED BY REDOX SWITCHING

Authors
PSILLAKIS E MAHER JP MCCLEVERTY JA WARD MD
Citation
E. Psillakis et al., MAGNETIC COMMUNICATION IN ACYCLIC MIXED-VALENCE TRIMOLYBDENUM COMPLEXES MEDIATED BY REDOX SWITCHING, Chemical communications, (7), 1998, pp. 835-836
Citations number
26
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
7
Year of publication
1998
Pages
835 - 836
Database
ISI
SICI code
1359-7345(1998):7<835:MCIAMT>2.0.ZU;2-A
Abstract
Reversible one-electron reduction converts the 'V-shaped' (dmpz)(3)]{O C(6)H(4)XpyMo(NO)[HB(dmpz)(3)]-Cl}(2)] (dmpz = 3,5-dimethylpyrazolyl; X = nothing, CH=CH or CH2CH2; py = pyridyl) with two unpaired electron s on the peripheral metals, whose magnetic exchange properties depend on X, into a monoanion having three unpaired paired spins on each meta l centre which engage in magnetic exchange in solution irrespective of X.