ISOLATED INFINITY(1) [TEO5] CHAINS OF OCT AHEDRA IN THE LEAD TELLURATE PB2TEO5

Authors
WEDEL B WULFF L MULLERBUSCHBAUM H
Citation
B. Wedel et al., ISOLATED INFINITY(1) [TEO5] CHAINS OF OCT AHEDRA IN THE LEAD TELLURATE PB2TEO5, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 53(3), 1998, pp. 287-290
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
53
Issue
3
Year of publication
1998
Pages
287 - 290
Database
ISI
SICI code
0932-0776(1998)53:3<287:II[COO>2.0.ZU;2-9
Abstract
Single crystals of Pb2TeO5 have been prepared by flux techniques. X-ra y investigations showed a new crystal structure with monoclinic symmet ry, space group C-s(4)-Cc, a = 13.099(3), b = 5.714(1), c = 7.520(2) A ngstrom, beta = 123,80(3)degrees, Z = 4. Pb2TeO5 is characterized by ( 1)(infinity)[TeO5] chains of octahedra isolated from each other and in corporated into an edge, corner and face connected frame of PbO7 polyh edra. Possible positions of the lone pair of electrons of Pb2+ are est imated by calculations of Coulomb terms of lattice energy.