The excitation energies and the probabilities for radiative and radiat
ionless decays of hollow atom states belonging to the 2s(2)2p, 2s2p(2)
and 2p(3) configurations have been calculated on the basis of perturb
ation theory method (1/Z-expansion) in a broad range of values of atom
ic number Z. Our results agree well with the first observation of thes
e states and the theoretical and experimental results obtained recentl
y for neutral Li atoms. It should be noted that the 1/Z expansion meth
od gives more accurate results for ions than for neutral systems, beca
use of the limited number of coefficients of 1/Z expansion calculated
in this work. In this case the good agreement provided by our results
for neutral system allows us to believe that our data for the same tri
ply excited states with Z > 3 should be used for prediction of new exp
eriments with these states.