SYNTHETIC AND SPECTROSCOPIC ASPECTS OF SOME MALEONITRILE DITHIOLATE COMPLEXES OF RUTHENIUM(II)

Authors
GUPTA DK SISODIA OS SAHAY AN PANDEY DS
Citation
Dk. Gupta et al., SYNTHETIC AND SPECTROSCOPIC ASPECTS OF SOME MALEONITRILE DITHIOLATE COMPLEXES OF RUTHENIUM(II), Synthesis and reactivity in inorganic and metal-organic chemistry, 28(3), 1998, pp. 355-365
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
28
Issue
3
Year of publication
1998
Pages
355 - 365
Database
ISI
SICI code
0094-5714(1998)28:3<355:SASAOS>2.0.ZU;2-N
Abstract
Reactions of [RuH(CO)Cl(PPh3)(3)] with Na2S2C2(CN)(2) (referred hereaf ter as Na(2)mnt) lead to the formation of [RuH(CO)(PPh3)(2) {S2C2(CN)( 2)}](-) which, upon treatment with [RuCp(EPh3)(2)Cl], yields neutral c omplexes with the general formulation [RuH(CO)(EPh3)(2){S2C2(CN)(2)}Ru Cp(EPh3)] (E = P, As, Sb). These complexes have been characterized by various physico-chemical techniques (elemental analyses, IR, H-1, C-13 and P-31 NMR and electronic spectra).