STERICALLY INDUCED CIS ISOMERISM IN AN SB(III) IMIDO DIMER - SYNTHESIS, STRUCTURE AND SOLUTION DYNAMICS OF [(ME2N)SB(MU-NDIPP)](2) (DIPP = 2,6-PR2IC6H3)

Authors
BESWICK MA HARMER CN HOPKINS AD PAVER MA RAITHBY PR WRIGHT DS
Citation
Ma. Beswick et al., STERICALLY INDUCED CIS ISOMERISM IN AN SB(III) IMIDO DIMER - SYNTHESIS, STRUCTURE AND SOLUTION DYNAMICS OF [(ME2N)SB(MU-NDIPP)](2) (DIPP = 2,6-PR2IC6H3), Polyhedron, 17(5-6), 1998, pp. 745-748
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
17
Issue
5-6
Year of publication
1998
Pages
745 - 748
Database
ISI
SICI code
0277-5387(1998)17:5-6<745:SICIIA>2.0.ZU;2-G
Abstract
The reaction of [Sb(NMe2)(3)] with the sterically bulky amine [DippNH( 2)] gives the unusual cia dimer [(Me2N)Sb(mu-NDipp)](2) 1, containing a puckered Sb2N2 core. H-1 NMR studies show that the cis conformation is retained in solution. (C) 1998 Elsevier Science Ltd. All rights res erved.