MOO((OPR)-PR-I)(4) DECOMPOSITION PATHWAYS ON AGING - SPONTANEOUS AND NEARLY QUANTITATIVE TRANSFORMATION INTO MO6O10((OPR)-PR-I)(12)

Authors
KESSLER VG SHEVELKOV AV BENGTSSONKLOO LA
Citation
Vg. Kessler et al., MOO((OPR)-PR-I)(4) DECOMPOSITION PATHWAYS ON AGING - SPONTANEOUS AND NEARLY QUANTITATIVE TRANSFORMATION INTO MO6O10((OPR)-PR-I)(12), Polyhedron, 17(5-6), 1998, pp. 965-968
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
17
Issue
5-6
Year of publication
1998
Pages
965 - 968
Database
ISI
SICI code
0277-5387(1998)17:5-6<965:MDPOA->2.0.ZU;2-2
Abstract
Liquid samples of MoO((OPr)-Pr-i)(4) (I), kept at room temperature in complete isolation from oxygen and moisture, nearly completely solidif y after approximately 2 months of storage. GLC-MS analysis of the liqu id residue showed it containing approximately equal amounts of (PrOH)- Pr-i and acetone and excess of (Pr2O)-Pr-i. Multinuclear NMR (C-13, O- 17 and Mo-95) investigation of this reaction in solution in toluene pr oved that acetone and ether elimination occur simultaneously. The soli d product of the reaction was identified as Mo6O10((OPr)-Pr-i)(12) (II ). (C) 1998 Elsevier Science Ltd. All rights reserved.