FIRST STRUCTURAL CHARACTERIZATION OF A ZINC-BIS(DIALKYLAMIDE) COMPOUND - ZN(N[C(CH3)(2)(CH2)(3)C(CH3)(2)])

Authors
REES WS JUST O SCHUMANN H WEIMANN R
Citation
Ws. Rees et al., FIRST STRUCTURAL CHARACTERIZATION OF A ZINC-BIS(DIALKYLAMIDE) COMPOUND - ZN(N[C(CH3)(2)(CH2)(3)C(CH3)(2)]), Polyhedron, 17(5-6), 1998, pp. 1001-1004
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
17
Issue
5-6
Year of publication
1998
Pages
1001 - 1004
Database
ISI
SICI code
0277-5387(1998)17:5-6<1001:FSCOAZ>2.0.ZU;2-V
Abstract
The reaction of two molar equivalents of Li{N[C(CH3)(2)(CH2)(3)C(CH3)( 2)]} with ZnCl2 in diethyl ether yields the title compound 1, which wa s characterized by H-1,C-13 and N-14 NMR, melting point, elemental ana lysis, mass spectrometry and single crystal X-ray diffraction. The str uctural characterization permits the first direct comparison of di(ary l)amide and di(triorganosilyl)amide examples with a di(alkyl)amide com position, thereby probing the nature of the Zn-N interaction. (C) 1998 Elsevier Science Ltd. All rights reserved.