A fluorozirconate glass doped with trivalent ytterbium ions has been l
aser cooled in vacuo from 298 to 277 K by optical pumping of the ions
at 1015 nm. The cooling effect arises from anti-Stokes fluorescence of
the laser-excited ions and by virtue of the near-unit fluorescence qu
antum efficiency for Yb3+ in sufficiently pure solid hosts. The sample
temperatures in the experiment are determined by measurement of the Y
b3+ emission spectrum; the value of the observed temperature change fr
om room temperature as a function of pump wavelength is successfully e
xplained in terms of a simple two-level model that includes the effect
of optical saturation. (C) 1998 Optical Society of America.