(-)-(1S)-TRICARBONYL(ETA(6)-2-METHOXYBENZYL ALCOHOL)CHROMIUM(0) AS A RESOLVING AGENT FOR TRICARBONYL (ETA(6)-2-METHOXYBENZOIC ACID)CHROMIUM(0)

Citation
P. Delbuttero et al., (-)-(1S)-TRICARBONYL(ETA(6)-2-METHOXYBENZYL ALCOHOL)CHROMIUM(0) AS A RESOLVING AGENT FOR TRICARBONYL (ETA(6)-2-METHOXYBENZOIC ACID)CHROMIUM(0), Gazzetta chimica italiana, 127(10), 1997, pp. 547-549
Citations number
32
Categorie Soggetti
Chemistry
Journal title
ISSN journal
00165603
Volume
127
Issue
10
Year of publication
1997
Pages
547 - 549
Database
ISI
SICI code
0016-5603(1997)127:10<547:(AAAR>2.0.ZU;2-F
Abstract
Racemic tricarbonyl(eta(6)-2-methoxybenzoic acid)chromium(0) has been resolved by esterification with the enantiomerically pure tricarbonyl( eta(6)-2-methoxybenzyl alcohol)chromium(0). After hydrolysis, the reso lving agent was recovered in 66% yield and with unchanged optical puri ty.