ABOUT THE TIMING OF WAGNER-MEERWEIN AND NAMETKIN REARRANGEMENTS, 6,2-HYDRIDE SHIFT, PROTON ELIMINATION AND CATION TRAPPING IN 2-NORBORNYL CARBOCATIONS

Authors
MARTINEZ AG VILAR ET FRAILE AG FERNANDEZ AH CERERO SD JIMENEZ FM
Citation
Ag. Martinez et al., ABOUT THE TIMING OF WAGNER-MEERWEIN AND NAMETKIN REARRANGEMENTS, 6,2-HYDRIDE SHIFT, PROTON ELIMINATION AND CATION TRAPPING IN 2-NORBORNYL CARBOCATIONS, Tetrahedron, 54(18), 1998, pp. 4607-4614
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
18
Year of publication
1998
Pages
4607 - 4614
Database
ISI
SICI code
0040-4020(1998)54:18<4607:ATTOWA>2.0.ZU;2-L
Abstract
The reaction of different substituted 2-norbornanones 1 with triflic a nhydride in the presence of nitriles 6 is carried out in order to stud y the factors that influence on the different reaction possibilities o f 2-norbornyl carbocations. The syntheses of interesting annulated pyr imidine derivatives 10 and conformationally rigid 1,3 disubstituted pr oducts are described. (C) 1998 Elsevier Science Ltd. All rights reserv ed.