ENANTIOSELECTIVITY AND DIASTEREOSELECTIVITY IN THE HYDROLYSIS OF ACYLALS AND STRUCTURALLY RELATED ESTERS OF SECONDARY ALCOHOLS WITH CANDIDA-RUGOSA LIPASE

Authors
ANGELIS YS SMONOU I
Citation
Ys. Angelis et I. Smonou, ENANTIOSELECTIVITY AND DIASTEREOSELECTIVITY IN THE HYDROLYSIS OF ACYLALS AND STRUCTURALLY RELATED ESTERS OF SECONDARY ALCOHOLS WITH CANDIDA-RUGOSA LIPASE, Tetrahedron letters, 39(18), 1998, pp. 2823-2826
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
18
Year of publication
1998
Pages
2823 - 2826
Database
ISI
SICI code
0040-4039(1998)39:18<2823:EADITH>2.0.ZU;2-7
Abstract
Comparative studies of enantioselectivities and diastereoselectivities in the hydrolysis reactions of acylals and 50:50 threo-erythro mixtur es of the esters of related secondary alcohols with Candida rugosa lip ase gave significant information about the reactivity order in the enz ymatic hydrolysis of acylals. (C) 1998 Elsevier Science Ltd. All right s reserved.