OPTIMIZATION AND COMPARATIVE-STUDY OF THE ROOM-TEMPERATURE PHOSPHORESCENCE OF ACENAPHTHENE IN BETA-CYCLODEXTRIN IN THE PRESENCE OF 2 BROMOALCOHOLS

Authors
CARRETERO AS BLANCO CC GUTIERREZ AF DELAPENA AM
Citation
As. Carretero et al., OPTIMIZATION AND COMPARATIVE-STUDY OF THE ROOM-TEMPERATURE PHOSPHORESCENCE OF ACENAPHTHENE IN BETA-CYCLODEXTRIN IN THE PRESENCE OF 2 BROMOALCOHOLS, Applied spectroscopy, 52(3), 1998, pp. 420-425
Citations number
22
Categorie Soggetti
Instument & Instrumentation",Spectroscopy
Journal title
Applied spectroscopy → ACNP
ISSN journal
00037028
Volume
52
Issue
3
Year of publication
1998
Pages
420 - 425
Database
ISI
SICI code
0003-7028(1998)52:3<420:OACOTR>2.0.ZU;2-F
Abstract
A multivariate optimization approach, using a central composite blocke d cube-star design, has been carried out to optimize the room-temperat ure phosphorescence (RTP) of a ternary complex between a polycyclic ar omatic hydrocarbon (acenaphthene), beta-cyclodextrin. and two bromoalc ohols (2-bromoethanol and 2,3-dibromopropanol). A comparative study of the effect of the two bromoalcohols in the phosphorescence response h as shown that the highest RTP emission from acenaphthene included in b eta-CD is obtained with 2,3-dibromopropanol. An RTP determination meth od for acenaphthene has been proposed. Calibration graphs range betwee n 50 and 250 ng mL(-1), and a detection limit of 24 ng mL(-1) has been established.