ENERGETICS OF METAL-LIGAND MULTIPLE BONDS - A COMBINED SOLUTION THERMOCHEMICAL AND AB-INITIO QUANTUM-CHEMICAL STUDY OF M=O BONDING IN GROUP-6 METALLOCENE OXO COMPLEXES

Citation
L. Luo et al., ENERGETICS OF METAL-LIGAND MULTIPLE BONDS - A COMBINED SOLUTION THERMOCHEMICAL AND AB-INITIO QUANTUM-CHEMICAL STUDY OF M=O BONDING IN GROUP-6 METALLOCENE OXO COMPLEXES, Journal of the American Chemical Society, 120(13), 1998, pp. 3111-3122
Citations number
125
Categorie Soggetti
Chemistry
ISSN journal
00027863
Volume
120
Issue
13
Year of publication
1998
Pages
3111 - 3122
Database
ISI
SICI code
0002-7863(1998)120:13<3111:EOMMB->2.0.ZU;2-G
Abstract
In this paper, we report a synthetic; molecular structure, thermochemi cal, and ab initio Hartree-Fock/Moller-Plesset level study of bonding and bonding energetics in the group 6 metallocene oxo series Cp2Mo/(Me Cp)(2)MO, M = Cr, Mo, W. Efficient, high-yield syntheses of the pairs Cp2MH2/(MeCp)(2)MH2, Cp2MCl2/(MeCp)(2)MCl2, and Cp2MO/(MeCp)(2)MO wher e M = Mo or W are reported. The molecular structure of (MeCp)(2)WO fea tures a ''bent sandwich'' geometry with a W=O distance of 2.04(1) Angs trom and an average W-C(Cp) distance of 2.371(8) Angstrom. Thus, W-C(C p) exhibits a similar to 0.07 Angstrom elongation over the correspondi ng distance in typical Cp2WX2 complexes and a W=O distance which appea rs to be elongated versus what might be expected for a formal triple b ond. D(M=O) values obtained from (MeCp)(2)MO silanolytic (Me3SiCl, Me2 SiI) batch titration calorimetry are very large: 110(11) kcal/mol (M = Mo) and 132(10) kcal/mol (M = W). The corresponding D(W-OTMS) value i s determined to be 65(18) kcal/mol. Ab initio relativistic core potent ial calculations reveal significantly weakened M-Cp bonding versus tha t in the corresponding Cp2MCl2 compounds, weakened M=O bonding due to population of M-O st antibonding levels, and a pronounced accumulation of negative charge on the oxo ligand (consistent with observed nucleo philicity of these complexes). Calculated Cp(2)MCh and Cp2MO molecular geometries and D(M=O) values at the MP2 level are in favorable agreem ent with experiment. The D(M=O) and D(M-O) data provide significant in sight into the chemistry of Cp2MO complexes, especially in regard to c onstraints on oxo transfer as well as oxametallacycle formation and sc ission processes.