R. Schrebler et al., STUDY OF THE ANILINE OXIDATION PROCESS AND CHARACTERIZATION OF PANI FILMS BY ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY, Synthetic metals, 93(3), 1998, pp. 187-192
The initial stages of the electropolymerization process of aniline on
a Pt electrode in acid aqueous solutions (H2SO4 and HClO4), as well as
the properties of the films formed at potentials corresponding to the
first redox couple where the conducting reversible oxidized polymer s
tate is generated, have been studied by electrochemical impedance spec
troscopy (EIS). The kinetic parameters associated with the charge tran
sfer reaction during the monomer oxidation and the concomitant diffusi
on process to generate an oligomeric high-density region near the elec
trode surface were calculated. The analysis of impedance data clearly
shows that the frequency response of polyaniline (Pani) films is depen
dent on the nature of the electrolyte in which the films were prepared
. The electrochemical response of the Pani films formed in the presenc
e of HClO4 gives rise to the conclusion that the rate of the redox pro
cess become slower than that in H2SO4. (C) 1998 Elsevier Science S.A.
All rights reserved.