The study investigates pollution by micro-organic contaminants in rive
rine systems in NE England with the following four key objectives: (1)
to establish the range and concentrations of micro-organic compounds
in relation to land use; (2) investigate how the type and concentratio
ns of micro-organics can vary seasonally; (3) compare bed-sediment and
suspended-sediment concentrations, and to (4) assess the use of 'whol
e-water' samples as indicators of environmental water quality in parti
cular with respect to the ecotoxicological impact of contaminant-laden
sediments within fluvial, systems. Waters, bed-and suspended sediment
s were collected from six freshwater tributaries of the Humber river a
t quarterly intervals during the period July 1995-1996. A wide range o
f micro-organic contaminants were analyzed by GC/MS and GC/NPD, chosen
on the basis of information provided through the UK Land Ocean Intera
ction Study (LOIS) core monitoring and additional data regarding water
quality and land-use within the catchment. Thirty compounds were targ
eted including a range of pesticide groups, e.g. triazines, oganophosp
horus and synthetic pyrethroids, in addition to other compounds of con
cern including polyaromatic hydrocarbons, e.g. fluoranthene and pyrene
, and a surfactant residue, nonylphenol. The results show the presence
of a wide range of micro-organic contaminants associated with river s
ediments. The high concentration of compounds associated with both bed
and suspended sediments appears unrelated to the concentrations measu
red in the dissolved phase. Greater concentrations of contaminants are
found associated with the industrial southern rivers, Aire, Calder an
d Don. However, considerable temporal variation in the concentrations
associated with sediment has been shown. It is suggested that these va
riations reflect a number of factors such as differences in land-use a
nd the effect of the seasonal application of contaminants in addition
to differences in the sediment characteristics and hence the potential
of the sediment to remove or release a contaminant. It is shown that
river sediments can act as a 'sink' and potential secondary source of
micro-organic contaminants within fluvial systems. The implication of
such an association is also shown to be significant in terms of the ec
otoxicological impact of micro-organic contaminants. This is demonstra
ted for cis-and trans-permethrin for which the calculated porewater co
ncentrations in some rivers are sufficient to cause adverse effects on
benthic fauna. (C) 1998 Elsevier Science B.V.