SYNTHESIS AND NONLINEAR-OPTICAL PROPERTIES OF (N-ALKYLPYRROL-2-YL)SQUARAINE DERIVATIVES - PART-2

Two squaraine dyes, bis(5-ethyl-1-octadecylpyrral-2-gl)squaraine (Et-P y) and -dimethyl-4-ethyl-1-octadecylpyrrol-2-yl)squaraine (MeEt-Py) ha ve been synthesised and studied as Langmuir-Blodgett (LB) monolayers u sing atomic force microscopy (AFM), angle dependent X-ray photoelectro n spectroscopy (ADXPS) and grazing incidence X-ray diffraction (GIXD). Additional investigations include both their linear and second-order non-linear optical properties, the latter giving d(eff) = 1.5 +/- 0.2 pm V-1 for Et-Py and 1.1 +/- 0.2 pm V-1 for MeEt-Py, Comparisons with the previously reported dyes, bis(1-octadecylpyrrol-2-yl)squaraine (Py ) and bis(3,5-dimethyl-1-octadecylpyrrol-2-yl) (Me-Py) reveal that Me- Py is the only one of the four which deposits as ordered, densely pack ed LB firms which allows further studies on Me-Py so as to ascertain a valid mechanism for the occurrence of second harmonic generation (SHG ) in these centrosymmetric molecules. The results presented demonstrat e that the experimentally observed SHG in squaraines arises from a sur face induced orientational effect where higher SHG is achieved if the squaraine head-group is essentially perpendicular to the required hydr ophilic substrate.