C. Loisy et A. Pascal, INDURATED CARBONATE HORIZON IN CHALKY CHA MPAGNE - FUNCTION OF DIAGENESIS AND BIOLOGICAL EFFECTS UNDER TEMPERATE CLIMATE, Bulletin de la Societe geologique de France, 169(2), 1998, pp. 189-201
Indurated carbonate horizons in Champagne spread out on the top of per
iglacial cryoturbated chalk formation in contact with the present day
soil or a palaeosol. The indurated carbonate horizon appears as a disc
ontinuous conglomeratic hardpan composed by cryoclastic chalky sands a
nd gravels coated by cemented limey-clayey silts (binding material). M
icromorphologically, the binding material is composed of five entities
: (1) matrix with detrital elements (composed of elementary chalk grai
ns, quartz, feldspars, glauconite, and organic matter); (2) microspar
cement (composed of calcite crystals 4-10 mu m in size, due to coalesc
ence of elementary chalky grains of the matrix with detrital elements)
; (3) sparry cement (with spar crystallizations up to 20 mu m in width
); (4) calcitic acicular phase (composed of monocrystalline needles of
MA type. typically 7-30 mu m long); (5) matrix of needles and micro-n
eedles frame (composed of grains of the matrix with detrital elements
in a micrite thrombolitic cement with M microneedles and MA needles).
Fluorescent microscopy observations coupled with quantitative image an
alysis allowed the respective part of each entitle in the cementation
to be characterized. Fongical and bacterial biomineralizations affect
mainly the top of the indurated horizons. The physico-chemical factors
(recrystallization of the matrix with detrital elements to microspar
cement, then to sparry cement) appear to be the predominant process wh
ich explains most of cement in bottom and in the middle zone of the in
durated layer. The observations of five entities show a physico-chemic
al process (diagenesis) and a process of biomineralization followed by
diagenesis (biodiagenesis). The two diagenetic processes of induratio
n are complementary: (1) the physico-chemical sequence of recrystalliz
ation is the major process of cementation and (2) the biodiagenesis wi
th growth of calcite needle-fibres that causes porosity decrease and m
icrite thrombolitic cementation around the pores.