SYNTHESIS, DERIVATIZATION, AND STRUCTURAL CHARACTERIZATION OF [MN(CNC6H3ME2-2,6)(5)](-), A 5-COORDINATE ISONITRILATE COMPLEX CONTAINING MN-I

Authors
UTZ TL LEACH PA GEIB SJ COOPER NJ
Citation
Tl. Utz et al., SYNTHESIS, DERIVATIZATION, AND STRUCTURAL CHARACTERIZATION OF [MN(CNC6H3ME2-2,6)(5)](-), A 5-COORDINATE ISONITRILATE COMPLEX CONTAINING MN-I, Chemical communications, (9), 1997, pp. 847-848
Citations number
32
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
9
Year of publication
1997
Pages
847 - 848
Database
ISI
SICI code
1359-7345(1997):9<847:SDASCO>2.0.ZU;2-D
Abstract
Naphthalenide reduction of [Mn(CNC6H3Me2-2,6)(5)Cl] forms solutions of trigonal-bipyramidal [Mn(CNC6H3Me2-2,6)(5)](-), as established by an X-ray diffraction study of a [K(18-C-6)(dme)](+) salt and derivatizati on with SnClPh3 to give [Mn(CNC6H3Me2-2,6)(5)(SnPh3)].