HYDROTHERMAL SYNTHESIS AND STRUCTURAL DETERMINATIONS OF SOME NEW POLYOXOFLUOROVANADATES [V14O36F4](8-) INTERLEAVED BY WATER-MOLECULES AND ORGANIC CATIONS NH3(CH2)(N)NH3 (N=4-6)

Authors
NINCLAUS C RIOU D FEREY G
Citation
C. Ninclaus et al., HYDROTHERMAL SYNTHESIS AND STRUCTURAL DETERMINATIONS OF SOME NEW POLYOXOFLUOROVANADATES [V14O36F4](8-) INTERLEAVED BY WATER-MOLECULES AND ORGANIC CATIONS NH3(CH2)(N)NH3 (N=4-6), Chemical communications, (9), 1997, pp. 851-852
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
9
Year of publication
1997
Pages
851 - 852
Database
ISI
SICI code
1359-7345(1997):9<851:HSASDO>2.0.ZU;2-I
Abstract
[V14O36F4](8-) polyanions are built up from two trimers of three edge- sharing VO5F octahedra, two dimers of two square pyramids related by t heir basal plane, two VO4 tetrahedra and two VO4F trigonal bipyramids; between them are intercalated water molecules and diprotonated amines which stabilize the structures by hydrogen bonds.