USE OF ELECTROSPRAY-IONIZATION MASS-SPECTROMETRY TO CHARACTERIZE CHIRAL REACTIVE INTERMEDIATES IN A TITANIUM ALKOXIDE MEDIATED SULFOXIDATION REACTION

Authors
BONCHIO M LICINI G MODENA G MORO S BORTOLINI O TRALDI P NUGENT WA
Citation
M. Bonchio et al., USE OF ELECTROSPRAY-IONIZATION MASS-SPECTROMETRY TO CHARACTERIZE CHIRAL REACTIVE INTERMEDIATES IN A TITANIUM ALKOXIDE MEDIATED SULFOXIDATION REACTION, Chemical communications, (9), 1997, pp. 869-870
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
9
Year of publication
1997
Pages
869 - 870
Database
ISI
SICI code
1359-7345(1997):9<869:UOEMTC>2.0.ZU;2-3
Abstract
The ESIMS technique, combined with H-1 NMR evidence, provides a precis e inventory of the catalytic Ti-IV precursors and the characterization of the reactive peroxometal complex involved in enantioselective sulf oxidation employing the Ti-IV-homochiral trialkanolamine-alkylhydroper oxide system.