FIRST MONONUCLEAR ORGANOMETALLICS OF MO-II AND MO-III CONTAINING TERMINAL HYDROXIDE LIGANDS - X-RAY STRUCTURE OF [MO(ETA(5)-C5H5)(OH)(PME3)(3)]BF4

Authors
FETTINGER JC KRAATZ HB POLI R QUADRELLI EA
Citation
Jc. Fettinger et al., FIRST MONONUCLEAR ORGANOMETALLICS OF MO-II AND MO-III CONTAINING TERMINAL HYDROXIDE LIGANDS - X-RAY STRUCTURE OF [MO(ETA(5)-C5H5)(OH)(PME3)(3)]BF4, Chemical communications, (9), 1997, pp. 889-890
Citations number
34
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
9
Year of publication
1997
Pages
889 - 890
Database
ISI
SICI code
1359-7345(1997):9<889:FMOOMA>2.0.ZU;2-F
Abstract
The new complexes [Mo(eta(5)-C5H5)(OH)(PMe3)(2)] and [Mo(eta(5)-C5H5)( OH)(PMe3)(3)](+) are unique examples of electronically unsaturated org anometallics of Mo-II and Mo-III containing terminal hydroxide ligands ; they show no tendency to dimerize with formation of hydroxo-bridges.