A NOVEL ORGANOMETALLIC OXIDE CLUSTER WITH MULTI-VALLEY SITES - SYNTHESIS AND STRUCTURE OF [NBU4N](2)[((ETA(5)-C5ME5)RH)(2)MO6O20(OME)(2)] AND ITS FRAMEWORK TRANSFORMATIONS

Authors
TAKARA S NISHIOKA T KINOSHITA I ISOBE K
Citation
S. Takara et al., A NOVEL ORGANOMETALLIC OXIDE CLUSTER WITH MULTI-VALLEY SITES - SYNTHESIS AND STRUCTURE OF [NBU4N](2)[((ETA(5)-C5ME5)RH)(2)MO6O20(OME)(2)] AND ITS FRAMEWORK TRANSFORMATIONS, Chemical communications, (9), 1997, pp. 891-892
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
9
Year of publication
1997
Pages
891 - 892
Database
ISI
SICI code
1359-7345(1997):9<891:ANOOCW>2.0.ZU;2-3
Abstract
A novel organometallic oxide cluster [NBu4n](2)[{eta(5)-C5Me5)Rh}(2)Mo 6O20(OMe)(2)] 1 with multi-valley sites is synthesized by the reaction of [NBu4n](2)[Mo2O7] and {(eta(5)-C5Me5)RhCl(mu-Cl)}(2)] in a molar r atio of 4:1 in methanol, and displays unique framework transformations upon treatment with organometallic and oxometalate compounds.