Cc. Chou et al., STRUCTURE CONTROL OF PULSED-LASER-DEPOSITED PB0.6SR0.4TIO3 LA0.5SR0.5COO3 THIN-FILMS ON VARIOUS SUBSTRATES/, Ferroelectrics, 206(1-4), 1998, pp. 393-405
Structure development is an important issue for the growth of ferroele
ctric thin film. In the present experiment, Pb0.6Sr0.4TiO3(PSrT)/La0.5
Sr0.5CoO3 (LSCO) thin films have been grown on various substrates, suc
h as: single crystal Si with (100) and (111) orientations, Au/Si, Pt/S
i and glass, using XeCl excimer laser (wavelength = 308 nm) under vari
ous processing conditions. X-ray diffraction results show that highly
(100)-oriented LSCO films can be deposited successfully under appropri
ate processing conditions regardless the type of the substrate. PSrT f
ilms can be deposited upon LSCO layer with the same structure arrangem
ents if LSCO can develop desired structures. It appears that appropria
te processing parameters are more important than lattice parameter con
sideration for growing LSCO films using pulsed laser deposition. Micro
structure investigations indicate that the substrate with an amorphous
surface layer may help the development of the desired structure.