KINETICS OF ETHYLENE REACTION WITH PALLADIUM(II) CHLORIDE COMPLEXES SUPPORTED ON SILICA-GEL

Authors
TRETYAKOV VP ZIMTSEVA GP RUDAKOV ES
Citation
Vp. Tretyakov et al., KINETICS OF ETHYLENE REACTION WITH PALLADIUM(II) CHLORIDE COMPLEXES SUPPORTED ON SILICA-GEL, Kinetics and catalysis, 39(2), 1998, pp. 211-216
Citations number
14
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
39
Issue
2
Year of publication
1998
Pages
211 - 216
Database
ISI
SICI code
0023-1584(1998)39:2<211:KOERWP>2.0.ZU;2-7
Abstract
An experimental proof is presented for the idea that the rate constant s for the reactions of ethylene with solid PdCl2/SiO2 catalysts can be measured by the kinetic distribution method in the absence of a solve nt. The kinetics of ethylene oxidation to acetaldehyde over PdCl2/SiO2 was studied at 300 K. The rate constant of the ethylene reaction with Pd(II) binuclear complexes was found to be higher than that of the et hylene reaction with mononuclear complexes.