CALCULATION AND ANALYSIS OF KINETIC CHARACTERISTICS OF DROPLET NUCLEATION ON THE MACROSCOPIC CONDENSATION NUCLEI UNDER THE CONDITIONS OF GRADUAL CREATION OF THE METASTABLE STATE IN VAPOR

Citation
Fm. Kuni et al., CALCULATION AND ANALYSIS OF KINETIC CHARACTERISTICS OF DROPLET NUCLEATION ON THE MACROSCOPIC CONDENSATION NUCLEI UNDER THE CONDITIONS OF GRADUAL CREATION OF THE METASTABLE STATE IN VAPOR, Colloid journal of the Russian Academy of Sciences, 60(2), 1998, pp. 179-190
Citations number
7
Categorie Soggetti
Chemistry Physical
ISSN journal
1061933X
Volume
60
Issue
2
Year of publication
1998
Pages
179 - 190
Database
ISI
SICI code
1061-933X(1998)60:2<179:CAAOKC>2.0.ZU;2-O
Abstract
The algorithm of the calculations of all principal kinetic characteris tics of nucleation of supercritical droplets under the gradual creatio n of the metastable state in vapor (total number of emerging droplets, beginning time and duration of droplet emergence, and dimensions of d roplets) was formulated. It was shown that under the given properties of the vapor-gas medium, the liquid condensing from it, as well as at given dimensions of condensation nuclei, the algorithm allows us to co ver the entire range of the characteristic time of the creation of the metastable state in vapor and that of the initial concentration of th e condensation nuclei admitted by the conditions of the theory applica bility. It was elucidated that the macroscopicity of condensation nucl ei results in more rigorous conditions of applicability. Based on the algorithm, numerical calculations demonstrated the ability of the theo ry proposed to make practical prospects in a rather wide range of exte rnal parameters of the theory. The theory was generalized for the case of the gradual creation, arbitrarily changing in time, of the metasta ble state in vapor.