A SUPRAMOLECULAR APPROACH TO THE CRYSTALLIZATION OF POLYNUCLEAR AQUA IONS - STRUCTURE AND MAGNETISM OF AN 18-CROWN-6 ADDUCT OF BIS(MU-HYDROXO)OCTAAQUADICHROMIUM(III) MESITYLENE-2-SULFONATE TRIHYDRATE

Authors
DRLJACA A HOCKLESS DCR MOUBARAKI B MURRAY KS SPICCIA L
Citation
A. Drljaca et al., A SUPRAMOLECULAR APPROACH TO THE CRYSTALLIZATION OF POLYNUCLEAR AQUA IONS - STRUCTURE AND MAGNETISM OF AN 18-CROWN-6 ADDUCT OF BIS(MU-HYDROXO)OCTAAQUADICHROMIUM(III) MESITYLENE-2-SULFONATE TRIHYDRATE, Inorganic chemistry, 36(10), 1997, pp. 1988
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
36
Issue
10
Year of publication
1997
Database
ISI
SICI code
0020-1669(1997)36:10<1988:ASATTC>2.0.ZU;2-L
Abstract
A supramolecular approach to the crystallization of polynuclear aqua i ons has been developed which utilizes the ability of the donor atoms o f macrocyclic ligands, such as 18-crown-6, to hydrogen-bond to coordin ated water molecules, thereby modifying the 3D II-bonding network that surrounds such ions in aqueous solution. The synthesis, X-ray structu re, and magnetic properties of [Cr-2(mu-OH)(2)(H2O)(8)][(H3C)(3)C6H2SO 3](4) . C12H24O6 . 3H(2)O are reported.