NEW BRIDGED ZIRCONOCENES FOR OLEFIN POLYMERIZATION - BINUCLEAR AND HYBRID STRUCTURES

Authors
SPALECK W KUBER F BACHMANN B FRITZE C WINTER A
Citation
W. Spaleck et al., NEW BRIDGED ZIRCONOCENES FOR OLEFIN POLYMERIZATION - BINUCLEAR AND HYBRID STRUCTURES, Journal of molecular catalysis. A, Chemical, 128(1-3), 1998, pp. 279-287
Citations number
17
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular catalysis. A, Chemical → ACNP
ISSN journal
13811169
Volume
128
Issue
1-3
Year of publication
1998
Pages
279 - 287
Database
ISI
SICI code
1381-1169(1998)128:1-3<279:NBZFOP>2.0.ZU;2-2
Abstract
Four newly synthesized bridged bisindenyl zirconocenes which are deriv atives of known structures have been tested in polymerizations of liqu id propylene with methylaluminoxane as cocatalyst. They include two as ymmetric and two binuclear systems which are suitable for isotactic po lymerization. Surprising differences from the behavior of similar syst ems (regiospecificity, chain termination) are found and discussed. (C) 1998 Published by Elsevier Science B.V.