A. Kotarba et al., IN-SITU CHARACTERIZATION OF AN IRON CATALYST BY POTASSIUM-ION DESORPTION AND ELECTRON-EMISSION MEASUREMENTS, Reaction kinetics and catalysis letters, 63(2), 1998, pp. 219-224
The surface conditions of an industrial iron catalyst were monitored i
n situ by work function measurements and measurements of thermal desor
ption of potassium ions. Changes in activation energy for potassium io
n desorption and iu work function values during catalyst activation an
d deactivation are discussed in terms of the potassium coverage and ch
emical composition of the catalyst surface.