Mechanically induced degradation crf diamond, as occurs during polishi
ng, is studied using total-energy pseudopotential calculations. The st
rong asymmetry in the rate of polishing between different directions o
n the diamond (110) surface is explained in terms of an atomistic mech
anism for nanogroove formation. The postpolishing surface morphology a
nd the nature of the polishing residue predicted by this mechanism are
consistent with experimental evidence.