SYNTHESIS AND ELECTRODE PROPERTIES OF 16-MEMBERED AZOCROWN AND AZOXYCROWN ETHERS - STRUCTURE OF TRIBENZO-16-AZOCROWN-6

Authors
LUBOCH E BIERNAT JF SIMONOV YA DVORKIN AA
Citation
E. Luboch et al., SYNTHESIS AND ELECTRODE PROPERTIES OF 16-MEMBERED AZOCROWN AND AZOXYCROWN ETHERS - STRUCTURE OF TRIBENZO-16-AZOCROWN-6, Tetrahedron, 54(19), 1998, pp. 4977-4990
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
19
Year of publication
1998
Pages
4977 - 4990
Database
ISI
SICI code
0040-4020(1998)54:19<4977:SAEPO1>2.0.ZU;2-6
Abstract
16-Membered benzoazo- and benzoazoxycrown ethers have been synthesized by reductive macrocyclization of respective bis(nitrophenoxy)oxaalkan es. The isomers of azocrown ethers were separated and E and Z structur es were ascribed. Behavior of the compounds as ionophores in ion-selec tive membrane electrodes has been studied. Structure of Z isomer of 16 -membered tribenzoazocrown ether has been determined. (C) 1998 Elsevie r Science Ltd. All rights reserved.