SYNTHESIS AND CHARACTERIZATION OF NEW DISILANE DERIVATIVES OF TUNGSTEN

Authors
PALITZSCH W BOHME U ROEWER G
Citation
W. Palitzsch et al., SYNTHESIS AND CHARACTERIZATION OF NEW DISILANE DERIVATIVES OF TUNGSTEN, Journal of organometallic chemistry, 552(1-2), 1998, pp. 213-219
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
552
Issue
1-2
Year of publication
1998
Pages
213 - 219
Database
ISI
SICI code
0022-328X(1998)552:1-2<213:SACOND>2.0.ZU;2-W
Abstract
By use of salt elimination, (eta(5)-C-5 Me4Et)W(CO)(3)SiMe2 SiMe2R (R = Me, Cl, Br), (eta(5)-C-5 Me4Et)W(CO)(3)SiMe2SiMe2 (eta(5)- C5Me4Et)W (CO)(3), (eta(5)-C9H7)W(CO)(3)SiMe2SiMe2Cl (C9H7 = indenyl) and a(5)-C 9H7)W(CO)(3)-SiMe2SiMe2(eta(5)-C9H7)W(CO)(3) were prepared and charact erized. A hydridotris(3,5-di-methylpyrazolyl)borate (Tp) stabilized t ungsten disilane complex, Tp W(CO)(2)SiMe2SiMe2Cl was prepared by nov el one pot synthesis, isolated and characterized. (C) 1998 Elsevier Sc ience S.A.